The glass transition temperature (Tg) is the point at which the polymer transitions from a rigid, glassy state to a soft, rubbery one. Below Tg, the insulation is dimensionally stable and mechanically strong. Above Tg, it softens, becomes susceptible to abrasion and compression, and — for self-bonding coils — the adhesive overcoat loses its structural function. Thermal design must ensure that hotspot temperatures under worst-case conditions (maximum duty cycle, highest ambient, aged thermal resistance) remain below Tg with margin.
The thermal class is usually taken to give 20.000 h of lifetime at the rated thermal class temperature. At lower operating temperatures, lifetime extends dramatically, following Arrhenius: every 10 °C doubles the lifetime. Above this temperature it halves per 10 °C, which relationship is used to estimate service life from accelerated ageing test data.
Multi-layer insulation systems are common in higher-performance wire — for example, a polyesterimide base coat for thermal resistance topped with polyamide-imide for abrasion protection. The self-bonding overcoat, where present, sits on top as the outermost layer.
Solderable insulation (notably polyurethane) allows direct soldering without stripping, simplifying lead termination. The lower thermal class limits its use to applications where hotspot temperatures remain well below 155 °C. Higher-thermal-class insulations require mechanical or laser stripping before soldering.